Excess electron kinetics by dispersive conductivity: A proposition

Robert Schiller, Gabor Nagy

Research output: Contribution to journalArticle

Abstract

A proposition for the simultaneous experimental determination of mobility and scavenger rate coefficient of localized excess electrons is exposed. Based on an earlier theory [Schiller, R., Balog, J., Nagy, G., 2005. Continuous-time random-walk theory of interfering diffusion and chemical reaction with an application to electrochemical impedance spectra of oxidized Zr-1%Nb. J. Chem. Phys. 123, 094704-1-7], it is expected that the steady state conductivity of an insulating liquid, irradiated or illuminated in the presence of some scavenger, depends on frequency. By analyzing the frequency dependence one can obtain the values of the above material properties.

Original languageEnglish
Pages (from-to)1248-1250
Number of pages3
JournalRadiation Physics and Chemistry
Volume76
Issue number8-9
DOIs
Publication statusPublished - Aug 1 2007

Keywords

  • Conductivity
  • Excess electron
  • Photochemistry
  • Radiation chemistry
  • Random walk

ASJC Scopus subject areas

  • Radiation

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