Evidence for quasi-intramolecular acid-base reactions in solutions of transition metal ammine complexes

László Kótai, Tibor Horváth, K. Szentmihályi, Ágnes Keszler

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Abstract

We have investigated the effect of temperature on the postulated quasi-intramolecular acid-base reactions in aqueous solutions of Cu(NH3)4(MnO4)2 and Ag(NH3)2ClO4. Pure ammonium permanganate and perchlorate were obtained above 5°C and at room temperature, respectively, due to quasi-intramolecular acid-base reactions.

Original languageEnglish
Pages (from-to)293-294
Number of pages2
JournalTransition Metal Chemistry
Volume25
Issue number3
Publication statusPublished - 2000

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Metal complexes
Transition metals
Acids
Ammonium Compounds
Temperature
permanganic acid
perchlorate

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Evidence for quasi-intramolecular acid-base reactions in solutions of transition metal ammine complexes. / Kótai, László; Horváth, Tibor; Szentmihályi, K.; Keszler, Ágnes.

In: Transition Metal Chemistry, Vol. 25, No. 3, 2000, p. 293-294.

Research output: Contribution to journalArticle

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