Evidence for quasi-intramolecular acid-base reactions in solutions of transition metal ammine complexes

László Kótai, Tibor Horváth, Klára Szentmihályi, Ágnes Keszler

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

We have investigated the effect of temperature on the postulated quasi-intramolecular acid-base reactions in aqueous solutions of Cu(NH3)4(MnO4)2 and Ag(NH3)2ClO4. Pure ammonium permanganate and perchlorate were obtained above 5°C and at room temperature, respectively, due to quasi-intramolecular acid-base reactions.

Original languageEnglish
Pages (from-to)293-294
Number of pages2
JournalTransition Metal Chemistry
Volume25
Issue number3
DOIs
Publication statusPublished - Jan 1 2000

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Metals and Alloys
  • Materials Chemistry

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