Evaluation of catalytic activity of [RuClCp(dmoPTA)(PPh3)](OSO2CF3) in the isomerization of allylic alcohols in water (dmoPTA = 3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)

Adrian Mena-Cruz, Manuel Serrano-Ruiz, Pablo Lorenzo-Luis, Antonio Romerosa, A. Kathó, Ferenc Joó, Luis Manuel Aguilera-Sáez

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The catalytic activity of [RuClCp(HdmoPTA)(PPh3)](OSO2CF3) (1) and the dimeric complexes [RuClCp(PPh3)-μ-dmoPTA-1κP:2κ2N,N'-MCl2] (M = Ni (2), Co (3), Zn (4)) for the isomerization in water under Ar and ambient atmosphere of 1-octen-3-ol, 1-hepten-3-ol and 1-hexen-3-ol was investigated. A detailed study was devoted to the catalytic activity under Ar of 1 for the isomerization of 1-octen-3-ol.

Original languageEnglish
Pages (from-to)27-33
Number of pages7
JournalJournal of Molecular Catalysis A: Chemical
Volume411
DOIs
Publication statusPublished - Oct 8 2015

Fingerprint

nonanes
Isomerization
isomerization
catalytic activity
Catalyst activity
alcohols
Alcohols
Water
evaluation
water
atmospheres
3-hexen-1-ol
allyl alcohol
1-octen-3-ol
3,7-triaza-5-phosphabicyclo(3.3.1)nonane

Keywords

  • Allyl alcohols
  • Bimetallic complexes
  • Catalytic isomerization
  • Ruthenium
  • Water

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Process Chemistry and Technology

Cite this

Evaluation of catalytic activity of [RuClCp(dmoPTA)(PPh3)](OSO2CF3) in the isomerization of allylic alcohols in water (dmoPTA = 3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane). / Mena-Cruz, Adrian; Serrano-Ruiz, Manuel; Lorenzo-Luis, Pablo; Romerosa, Antonio; Kathó, A.; Joó, Ferenc; Aguilera-Sáez, Luis Manuel.

In: Journal of Molecular Catalysis A: Chemical, Vol. 411, 08.10.2015, p. 27-33.

Research output: Contribution to journalArticle

Mena-Cruz, Adrian ; Serrano-Ruiz, Manuel ; Lorenzo-Luis, Pablo ; Romerosa, Antonio ; Kathó, A. ; Joó, Ferenc ; Aguilera-Sáez, Luis Manuel. / Evaluation of catalytic activity of [RuClCp(dmoPTA)(PPh3)](OSO2CF3) in the isomerization of allylic alcohols in water (dmoPTA = 3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane). In: Journal of Molecular Catalysis A: Chemical. 2015 ; Vol. 411. pp. 27-33.
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abstract = "The catalytic activity of [RuClCp(HdmoPTA)(PPh3)](OSO2CF3) (1) and the dimeric complexes [RuClCp(PPh3)-μ-dmoPTA-1κP:2κ2N,N'-MCl2] (M = Ni (2), Co (3), Zn (4)) for the isomerization in water under Ar and ambient atmosphere of 1-octen-3-ol, 1-hepten-3-ol and 1-hexen-3-ol was investigated. A detailed study was devoted to the catalytic activity under Ar of 1 for the isomerization of 1-octen-3-ol.",
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AU - Mena-Cruz, Adrian

AU - Serrano-Ruiz, Manuel

AU - Lorenzo-Luis, Pablo

AU - Romerosa, Antonio

AU - Kathó, A.

AU - Joó, Ferenc

AU - Aguilera-Sáez, Luis Manuel

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AB - The catalytic activity of [RuClCp(HdmoPTA)(PPh3)](OSO2CF3) (1) and the dimeric complexes [RuClCp(PPh3)-μ-dmoPTA-1κP:2κ2N,N'-MCl2] (M = Ni (2), Co (3), Zn (4)) for the isomerization in water under Ar and ambient atmosphere of 1-octen-3-ol, 1-hepten-3-ol and 1-hexen-3-ol was investigated. A detailed study was devoted to the catalytic activity under Ar of 1 for the isomerization of 1-octen-3-ol.

KW - Allyl alcohols

KW - Bimetallic complexes

KW - Catalytic isomerization

KW - Ruthenium

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