ESTIMATION OF THE PHYSICO-CHEMICAL DATA OF HYDROCARBON REACTIONS BY RADIOCHEMICAL METHODS.

G. Foldiak, G. Cserep, I. Gyorgy, Z. Horvath, L. Wojnárovits

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Abstract

When alkane hydrocarbons are irradiated their chemical bonds dissociate in the following increasing order: primary less than secondary less than tertiary less than quarternary. The radiolysis of cycloalkanes is enhanced by their strain energy: Rings of 3-4 carbon atoms break up very easily, partly by a multiple C-C bond dissociation, while for C//7-C//1//0 cycloalkanes hydrogenation is more frequent. The radiolysis of alkenes is similar to that of alkanes, but the bond dissociation is influenced by the positive of the pi -bond. The G(H//2) value of aliphatic alkenes can be estimated from the H-increments of G(H//2).

Original languageEnglish
Pages (from-to)277-292
Number of pages16
JournalHungarian Journal of Industrial Chemistry
Volume2 Suppl 2
Publication statusPublished - 1974

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Cycloparaffins
Radiolysis
Alkanes
Alkenes
Hydrocarbons
Paraffins
Olefins
Chemical bonds
Strain energy
Hydrogenation
Carbon
Atoms

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)
  • Chemistry (miscellaneous)

Cite this

ESTIMATION OF THE PHYSICO-CHEMICAL DATA OF HYDROCARBON REACTIONS BY RADIOCHEMICAL METHODS. / Foldiak, G.; Cserep, G.; Gyorgy, I.; Horvath, Z.; Wojnárovits, L.

In: Hungarian Journal of Industrial Chemistry, Vol. 2 Suppl 2, 1974, p. 277-292.

Research output: Contribution to journalArticle

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