ESR study of the reaction of substituted nitrosobenzenes with aliphatic and saturated alkylaromatic hydrocarbons

P. Simon, L. Sümegi, A. Rockenbauer, I. Nemes, F. Tüdős

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Abstract

We have found that nitrosobenzenes spontaneously react with saturated hydrocarbons in the absence of oxygen and light. For interpretation of this general phenomenon a new reaction pathway has been assumed. In light of these results special care should be taken when applying nitrosobenzenes for inhibition and spin trapping as well as organic synthesis in saturated organic solvents, which are supposed to be inert.

Original languageEnglish
Pages (from-to)493-500
Number of pages8
JournalReaction Kinetics and Catalysis Letters
Volume15
Issue number4
DOIs
Publication statusPublished - Dec 1981

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ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

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