ESR of Ni2+ in AgCl and Isotope Effect in Crystal Field

M. Höhne, M. Stasiw, A. Watterich

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

ESR measurements are made on Ni‐doped AgCl at low temperatures. As in the case of AgBr:Ni, already investigated, a line with isotropic g‐value is found, due to isolated Ni2+. Moreover an angular dependent spectrum with nearly [100]‐axial symmetry is observed, which is attributed to complexes of Ni2+ with a silver vacancy. Contrary to the results on AgBr:Ni a structure of the anisotropic spectrum is observed in a small angular range, which may be explained only by the presence of very small orthorhombic perturbations. It is shown, that these orthorhombic perturbations of different quantities result from the variant distributions of both the isotopes 35Cl and 37Cl in the plane perpendicular to the axis of the centre.

Original languageEnglish
Pages (from-to)319-327
Number of pages9
Journalphysica status solidi (b)
Volume34
Issue number1
DOIs
Publication statusPublished - 1969

Fingerprint

Silver
Isotopes
isotope effect
Vacancies
crystal field theory
Paramagnetic resonance
perturbation
Crystals
isotopes
silver
Temperature
symmetry

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

Cite this

ESR of Ni2+ in AgCl and Isotope Effect in Crystal Field. / Höhne, M.; Stasiw, M.; Watterich, A.

In: physica status solidi (b), Vol. 34, No. 1, 1969, p. 319-327.

Research output: Contribution to journalArticle

Höhne, M. ; Stasiw, M. ; Watterich, A. / ESR of Ni2+ in AgCl and Isotope Effect in Crystal Field. In: physica status solidi (b). 1969 ; Vol. 34, No. 1. pp. 319-327.
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