Enhancement of fluorescent stability of 2,5-bis-2-(5-tert-butyl)-benzoxazolyl-thiophene (BBOT) containing LDPE films

G. Túry, R. Vabrik, I. Kása, K. Papp, I. Rusznák, G. T. Szabó, A. Víg, E. Kálmán

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The photostability of an optical brightener 2,5-bis-2-(5-tert-butyl)-benzoxazolyl-thiophene (BBOT) was investigated in solution and in LDPE films, respectively. The films were either laminated with light-screening transparent films containing ultrafine titanium dioxide or taken into multilayer systems containing a cross-linked component. It could be demonstrated that in the 250 through 400 nm irradiation spectra of BBOT the range between 250 and 300 nm was responsible for the light sensitivity of the system, whereas that between 300 and 400 nm was responsible for the fluorescence of the system. The influence of systems prepared with lamination and the cross-linked layer on the intensity of fluorescence of BBOT was determined. The simple lamination with titanium-dioxide-containing films did not prove to be an effective way of protection as both the photostability and the fluorescence intensity decreased simultaneously in systems of this type. The drop in light stability could be attributed to the migration of BBOT into the TiO2-containing film. A five-component system had to be produced for improving the light stability of the wanted product. LDPE film was linked to one side of a BBOT-containing film by means of a cross-linked adhesive. The other side of this film was linked to either another LDPE film or to TiO2-particle-filled LDPE film by the same type of cross-linked adhesive. The initial intensity of fluorescence dropped simultaneously by 15 to 40%. The light stability could be increased up to 400% of the original value.

Original languageEnglish
Pages (from-to)51-58
Number of pages8
JournalJournal of Photochemistry and Photobiology A: Chemistry
Volume114
Issue number1
Publication statusPublished - Mar 31 1998

Fingerprint

Thiophenes
Low density polyethylenes
Polyethylene
Thiophene
thiophenes
augmentation
Fluorescence
fluorescence
titanium oxides
Titanium dioxide
adhesives
laminates
Adhesives
Photosensitivity
Screening
Multilayers
screening
Irradiation

Keywords

  • BBOT
  • Cross-linked polymer
  • Fluorescence stability
  • High dispersity TiO
  • Laminated films
  • Multilayer films
  • Optical brightener
  • Photostability

ASJC Scopus subject areas

  • Bioengineering
  • Physical and Theoretical Chemistry

Cite this

Enhancement of fluorescent stability of 2,5-bis-2-(5-tert-butyl)-benzoxazolyl-thiophene (BBOT) containing LDPE films. / Túry, G.; Vabrik, R.; Kása, I.; Papp, K.; Rusznák, I.; Szabó, G. T.; Víg, A.; Kálmán, E.

In: Journal of Photochemistry and Photobiology A: Chemistry, Vol. 114, No. 1, 31.03.1998, p. 51-58.

Research output: Contribution to journalArticle

Túry, G. ; Vabrik, R. ; Kása, I. ; Papp, K. ; Rusznák, I. ; Szabó, G. T. ; Víg, A. ; Kálmán, E. / Enhancement of fluorescent stability of 2,5-bis-2-(5-tert-butyl)-benzoxazolyl-thiophene (BBOT) containing LDPE films. In: Journal of Photochemistry and Photobiology A: Chemistry. 1998 ; Vol. 114, No. 1. pp. 51-58.
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abstract = "The photostability of an optical brightener 2,5-bis-2-(5-tert-butyl)-benzoxazolyl-thiophene (BBOT) was investigated in solution and in LDPE films, respectively. The films were either laminated with light-screening transparent films containing ultrafine titanium dioxide or taken into multilayer systems containing a cross-linked component. It could be demonstrated that in the 250 through 400 nm irradiation spectra of BBOT the range between 250 and 300 nm was responsible for the light sensitivity of the system, whereas that between 300 and 400 nm was responsible for the fluorescence of the system. The influence of systems prepared with lamination and the cross-linked layer on the intensity of fluorescence of BBOT was determined. The simple lamination with titanium-dioxide-containing films did not prove to be an effective way of protection as both the photostability and the fluorescence intensity decreased simultaneously in systems of this type. The drop in light stability could be attributed to the migration of BBOT into the TiO2-containing film. A five-component system had to be produced for improving the light stability of the wanted product. LDPE film was linked to one side of a BBOT-containing film by means of a cross-linked adhesive. The other side of this film was linked to either another LDPE film or to TiO2-particle-filled LDPE film by the same type of cross-linked adhesive. The initial intensity of fluorescence dropped simultaneously by 15 to 40{\%}. The light stability could be increased up to 400{\%} of the original value.",
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