Enantiopure platinum(II) complexes have been synthetized with chiral stereodynamic diphosphine and diphosphinite ligands derived from 2,2-biphosphole through a dynamic chirality control upon coordination. Catalytic performances of these platinum complexes have been explored in asymmetric hydroformylation. All complexes proved to be effective catalysts with respect to chemoselectivity and regioselectivity but induced only low enantioselectivities.
- Enantiopure platinum complexes
- Stereodynamic ligands
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry