Elucidation of the conformations and absolute configurations of enantiomerically pure tetralin derivatives

Gábor Tóth, A. Simon, Torsten Linker, Frank Rebien, Jürgen Kraus, Gerhard Bringmann

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The enantioselective epoxidation of 1,2-dihydronaphthalenes (2) afforded optically active tetralin derivatives (3 and 4). The relative configurations and conformational behavior of all products were elucidated by detailed one-and two-dimensional 1H and 13C NMR methods. The last required stereochemical information, the absolute configuration of 4, attained through comparison of experimental and calculated CD spectra.

Original languageEnglish
Pages (from-to)53-59
Number of pages7
JournalMagnetic Resonance in Chemistry
Volume37
Issue number1
Publication statusPublished - Jan 1999

Fingerprint

Epoxidation
Conformations
Nuclear magnetic resonance
Derivatives
epoxidation
configurations
nuclear magnetic resonance
products
tetralin
1,2-dihydronaphthalene

Keywords

  • C NMR
  • H NMR
  • Circular dichroism; quantum chemical calculations
  • Conformational equilibrium
  • NMR

ASJC Scopus subject areas

  • Chemistry(all)
  • Physical and Theoretical Chemistry
  • Spectroscopy

Cite this

Elucidation of the conformations and absolute configurations of enantiomerically pure tetralin derivatives. / Tóth, Gábor; Simon, A.; Linker, Torsten; Rebien, Frank; Kraus, Jürgen; Bringmann, Gerhard.

In: Magnetic Resonance in Chemistry, Vol. 37, No. 1, 01.1999, p. 53-59.

Research output: Contribution to journalArticle

Tóth, Gábor ; Simon, A. ; Linker, Torsten ; Rebien, Frank ; Kraus, Jürgen ; Bringmann, Gerhard. / Elucidation of the conformations and absolute configurations of enantiomerically pure tetralin derivatives. In: Magnetic Resonance in Chemistry. 1999 ; Vol. 37, No. 1. pp. 53-59.
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