Electrospray ionization mass spectrometric analysis of highly reactive glycosyl halides

Attila Bokros, Annamaria Banfi, Zoltan Kupihar, Zoltan Kele, Tunde Zita Illyés, Janos Szolomajer, Lajos Kovacs

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Highly reactive glycosyl chlorides and bromides have been analysed by a routine mass spectrometric method using electrospray ionization and lithium salt adduct-forming agents in anhydrous acetonitrile solution, providing salient lithiated molecular ions [M+Li] +, [2M+Li] + etc. The role of other adduct-forming salts has also been evaluated. The lithium salt method is useful for accurate mass determination of these highly sensitive compounds.

Original languageEnglish
Pages (from-to)8351-8358
Number of pages8
JournalMolecules
Volume17
Issue number7
DOIs
Publication statusPublished - Jul 2012

Keywords

  • Electrospray mass spectrometry
  • Glycosyl halides
  • Lithium salts
  • Nanoelectrospray

ASJC Scopus subject areas

  • Analytical Chemistry
  • Chemistry (miscellaneous)
  • Molecular Medicine
  • Pharmaceutical Science
  • Drug Discovery
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Fingerprint Dive into the research topics of 'Electrospray ionization mass spectrometric analysis of highly reactive glycosyl halides'. Together they form a unique fingerprint.

  • Cite this