Electron paramagnetic resonance spectroscopic studies of the electron transfer reaction of Hantzsch ester and a pyrylium salt

K. Sebök-Nagy, D. Rózsár, L. G. Puskás, Balázs, T. Páli

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The oxidation of Hantzsch ester by a pyrylium cation takes place via electron-proton-electron transfer. The reaction was investigated with EPR spectroscopy using TEMPO and DMPO for inhibition and spin trapping, respectively, of the radicals appearing during the reaction. The present in-depth EPR study of the radical reactions of a NADH analogue indicate a complex electron transfer mechanism in the title reaction.

Original languageEnglish
Pages (from-to)29924-29927
Number of pages4
JournalRSC Advances
Volume8
Issue number52
DOIs
Publication statusPublished - Jan 1 2018

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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