Electron diffraction study of the molecular structure of bis(trimethylgermyl)ketene

Béla Rozsondai, I. Hargittai

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

The following parameters were obtained for a C2V model of the bis(trimethylgermyl) ketene molecule in the vapour phase by electron diffraction: r(Ge-C)av. = 1.946±0.005 Å, l(Ge-C)av. = 0.059 ±0.004 Å, r(C-H) = 1.131 ±0.011 Å, l(C-H) = 0.077±0.011 Å, r(C-C)= 1.274±0.015 Å, ∠Ge-C-Ge = 127.6±1.3°, ∠(H)C-Ge-C(H) = 108.1± 1.2°, l(Ge · Ge) = 0.090 ±0.010 Å, l(Ge · H) = 0.162±0.017 Å.

Original languageEnglish
Pages (from-to)53-64
Number of pages12
JournalJournal of Molecular Structure
Volume17
Issue number1
DOIs
Publication statusPublished - 1973

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Molecular Structure
Electron diffraction
Molecular structure
molecular structure
electron diffraction
Vapors
Electrons
vapor phases
Molecules
molecules
ketene

ASJC Scopus subject areas

  • Structural Biology
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Materials Science (miscellaneous)
  • Atomic and Molecular Physics, and Optics

Cite this

Electron diffraction study of the molecular structure of bis(trimethylgermyl)ketene. / Rozsondai, Béla; Hargittai, I.

In: Journal of Molecular Structure, Vol. 17, No. 1, 1973, p. 53-64.

Research output: Contribution to journalArticle

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abstract = "The following parameters were obtained for a C2V model of the bis(trimethylgermyl) ketene molecule in the vapour phase by electron diffraction: r(Ge-C)av. = 1.946±0.005 {\AA}, l(Ge-C)av. = 0.059 ±0.004 {\AA}, r(C-H) = 1.131 ±0.011 {\AA}, l(C-H) = 0.077±0.011 {\AA}, r(C-C)= 1.274±0.015 {\AA}, ∠Ge-C-Ge = 127.6±1.3°, ∠(H)C-Ge-C(H) = 108.1± 1.2°, l(Ge · Ge) = 0.090 ±0.010 {\AA}, l(Ge · H) = 0.162±0.017 {\AA}.",
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