Electron diffraction and vibrational spectroscopic investigation of the molecular structure of (chloromethyl)trichlorosilane

E. Vajda, T. Székely, I. Hargittai, A. K. Maltsev, E. G. Baskir, O. M. Nefedov, J. Brunvoll

Research output: Contribution to journalArticle

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Abstract

An electron diffraction analysis of the molecular structure of the title compound has been carried out, and related vibrational spectroscopic measurements and calculations have been made. The main bond lengths (rg and bond angles rα) are as follows: SiCl, 202.8(2); SiC, 185.1(10); CCl, 179.4(11); CH, 111.2(18) pm; SiCCl, 111.7(4);l ClSiC, 109.95(21)°. The conformation of the molecule is staggered. The barrier to internal rotation is estimated to be around 10 kJ mol-1.

Original languageEnglish
Pages (from-to)321-327
Number of pages7
JournalJournal of Organometallic Chemistry
Volume188
Issue number3
DOIs
Publication statusPublished - Apr 15 1980

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Bond length
Molecular Structure
Electron diffraction
Molecular structure
Conformations
molecular structure
electron diffraction
Electrons
methylidyne
Molecules
molecules
trichlorosilane

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

Cite this

Electron diffraction and vibrational spectroscopic investigation of the molecular structure of (chloromethyl)trichlorosilane. / Vajda, E.; Székely, T.; Hargittai, I.; Maltsev, A. K.; Baskir, E. G.; Nefedov, O. M.; Brunvoll, J.

In: Journal of Organometallic Chemistry, Vol. 188, No. 3, 15.04.1980, p. 321-327.

Research output: Contribution to journalArticle

Vajda, E. ; Székely, T. ; Hargittai, I. ; Maltsev, A. K. ; Baskir, E. G. ; Nefedov, O. M. ; Brunvoll, J. / Electron diffraction and vibrational spectroscopic investigation of the molecular structure of (chloromethyl)trichlorosilane. In: Journal of Organometallic Chemistry. 1980 ; Vol. 188, No. 3. pp. 321-327.
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AU - Baskir, E. G.

AU - Nefedov, O. M.

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