Electrochemical bromination of peracetylated glycals

Marija Čolović, Mirjana Vukićević, Dejan Šegan, Dragan Manojlović, Neso Sojic, László Somsák, Rastko D. Vukićević

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Bromination of glycals with tribromides formed in situ from bromine and different bromide salts in dichloromethane (DCM) or acetonitrile (AN) was found to give predominantly the products of anti addition of bromine from the C-6 side in high yields. The same selectivity, which was much higher compared to bromination with bromine alone, was achieved in bromination of these substrates by anodic generation of bromine from the same salts.

Original languageEnglish
Pages (from-to)29-34
Number of pages6
JournalAdvanced Synthesis and Catalysis
Volume350
Issue number1
DOIs
Publication statusPublished - Jan 2008

Keywords

  • Bromination
  • Constant current electrolysis
  • Glycals
  • Tribromides

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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  • Cite this

    Čolović, M., Vukićević, M., Šegan, D., Manojlović, D., Sojic, N., Somsák, L., & Vukićević, R. D. (2008). Electrochemical bromination of peracetylated glycals. Advanced Synthesis and Catalysis, 350(1), 29-34. https://doi.org/10.1002/adsc.200700310