Electrochemical and adsorption behaviour of ethylene glycol and its oxidative derivatives at platinum electrodes. Part II. Electrocatalytic transformations under steady-state experimental conditions at a platinized platinum electrode in acid medium

G. Horányi, V. E. Kazarinov, Yu B. Vassiliev, V. N. Andreev

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Abstract

Chemical transformations occurring in the course of electrocatalytic processes of ethylene glycol and its derivatives at a platinized platinum electrode are discussed. Both oxidation and reduction processes are considered. A reaction sequence leading to different intermediates in the course of the oxidation of ethylene glycol is formulated. Results obtained from adsorption and steady-state electrocatalytic studies are compared in order to throw light on the role of different types of adsorbed species in the electrocatalytic transformations.

Original languageEnglish
Pages (from-to)263-278
Number of pages16
JournalJournal of Electroanalytical Chemistry
Volume147
Issue number1-2
Publication statusPublished - May 25 1983

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Ethylene Glycol
Ethylene glycol
Platinum
Derivatives
Adsorption
Oxidation
Electrodes
Acids

ASJC Scopus subject areas

  • Electrochemistry
  • Analytical Chemistry
  • Chemical Engineering(all)

Cite this

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abstract = "Chemical transformations occurring in the course of electrocatalytic processes of ethylene glycol and its derivatives at a platinized platinum electrode are discussed. Both oxidation and reduction processes are considered. A reaction sequence leading to different intermediates in the course of the oxidation of ethylene glycol is formulated. Results obtained from adsorption and steady-state electrocatalytic studies are compared in order to throw light on the role of different types of adsorbed species in the electrocatalytic transformations.",
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T1 - Electrochemical and adsorption behaviour of ethylene glycol and its oxidative derivatives at platinum electrodes. Part II. Electrocatalytic transformations under steady-state experimental conditions at a platinized platinum electrode in acid medium

AU - Horányi, G.

AU - Kazarinov, V. E.

AU - Vassiliev, Yu B.

AU - Andreev, V. N.

PY - 1983/5/25

Y1 - 1983/5/25

N2 - Chemical transformations occurring in the course of electrocatalytic processes of ethylene glycol and its derivatives at a platinized platinum electrode are discussed. Both oxidation and reduction processes are considered. A reaction sequence leading to different intermediates in the course of the oxidation of ethylene glycol is formulated. Results obtained from adsorption and steady-state electrocatalytic studies are compared in order to throw light on the role of different types of adsorbed species in the electrocatalytic transformations.

AB - Chemical transformations occurring in the course of electrocatalytic processes of ethylene glycol and its derivatives at a platinized platinum electrode are discussed. Both oxidation and reduction processes are considered. A reaction sequence leading to different intermediates in the course of the oxidation of ethylene glycol is formulated. Results obtained from adsorption and steady-state electrocatalytic studies are compared in order to throw light on the role of different types of adsorbed species in the electrocatalytic transformations.

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