Electrochemical and adsorption behaviour of ethylene glycol and its oxidative derivatives at platinum electrodes. Part I. Adsorption and chemisorption processes

V. E. Kazarinov, Yu B. Vassiliev, V. N. Andreev, G. Horányi

Research output: Contribution to journalArticle

48 Citations (Scopus)

Abstract

The adsorption behaviour of ethylene glycol and its derivatives is discussed on the basis of the literature data and new experimental observations. Results obtained by different methods (pure electrochemical, radiotracer) are compared. Factors influencing the nature and composition of adsorbed species are analysed. It is stated that dehydrogenation, oxidation, hydrogenation and rupture of the C-C bond are the main processes determining the state of the strongly chemisorbed species. The behaviour of ethane, ethanol and ethylene glycol is compared and general schemes for the processes occurring with the adsorbed species formed from these compounds are proposed.

Original languageEnglish
Pages (from-to)247-261
Number of pages15
JournalJournal of Electroanalytical Chemistry
Volume147
Issue number1-2
Publication statusPublished - May 25 1983

Fingerprint

Ethylene Glycol
Chemisorption
Ethylene glycol
Platinum
Derivatives
Adsorption
Electrodes
Ethane
Dehydrogenation
Hydrogenation
Ethanol
Oxidation
Chemical analysis

ASJC Scopus subject areas

  • Electrochemistry
  • Analytical Chemistry
  • Chemical Engineering(all)

Cite this

Electrochemical and adsorption behaviour of ethylene glycol and its oxidative derivatives at platinum electrodes. Part I. Adsorption and chemisorption processes. / Kazarinov, V. E.; Vassiliev, Yu B.; Andreev, V. N.; Horányi, G.

In: Journal of Electroanalytical Chemistry, Vol. 147, No. 1-2, 25.05.1983, p. 247-261.

Research output: Contribution to journalArticle

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