Efficient synthesis of mixed phosphorates by the fragmentation-related phosphorylation of alcohols applying a 2-phosphabicyclo[2.2.2]octa-5,7-diene 2-oxide precursor

Helga Szelke, K. Ludányi, T. Imre, Zoltán Nagy, K. Vékey, L. Tőke, G. Keglevich

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1 Citation (Scopus)

Abstract

The photochemically induced phosphonylation of C1-C4 alcohols by the fragmentation of a P-ethoxy 2-phosphabicyclo[2.2.2]octa-5,7- diene 2-oxide (1) yielded the phosphonates (3) with two different alkoxy group efficiently, without the slightest extent of transesterification.

Original languageEnglish
Pages (from-to)4171-4178
Number of pages8
JournalSynthetic Communications
Volume34
Issue number22
DOIs
Publication statusPublished - 2004

Fingerprint

Organophosphonates
Phosphorylation
Transesterification
Oxides
Alcohols
alkoxyl radical

Keywords

  • Bridged P-heterocycles
  • Fragmentation
  • Phosphonates
  • Phosphorylation

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

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title = "Efficient synthesis of mixed phosphorates by the fragmentation-related phosphorylation of alcohols applying a 2-phosphabicyclo[2.2.2]octa-5,7-diene 2-oxide precursor",
abstract = "The photochemically induced phosphonylation of C1-C4 alcohols by the fragmentation of a P-ethoxy 2-phosphabicyclo[2.2.2]octa-5,7- diene 2-oxide (1) yielded the phosphonates (3) with two different alkoxy group efficiently, without the slightest extent of transesterification.",
keywords = "Bridged P-heterocycles, Fragmentation, Phosphonates, Phosphorylation",
author = "Helga Szelke and K. Lud{\'a}nyi and T. Imre and Zolt{\'a}n Nagy and K. V{\'e}key and L. Tőke and G. Keglevich",
year = "2004",
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T1 - Efficient synthesis of mixed phosphorates by the fragmentation-related phosphorylation of alcohols applying a 2-phosphabicyclo[2.2.2]octa-5,7-diene 2-oxide precursor

AU - Szelke, Helga

AU - Ludányi, K.

AU - Imre, T.

AU - Nagy, Zoltán

AU - Vékey, K.

AU - Tőke, L.

AU - Keglevich, G.

PY - 2004

Y1 - 2004

N2 - The photochemically induced phosphonylation of C1-C4 alcohols by the fragmentation of a P-ethoxy 2-phosphabicyclo[2.2.2]octa-5,7- diene 2-oxide (1) yielded the phosphonates (3) with two different alkoxy group efficiently, without the slightest extent of transesterification.

AB - The photochemically induced phosphonylation of C1-C4 alcohols by the fragmentation of a P-ethoxy 2-phosphabicyclo[2.2.2]octa-5,7- diene 2-oxide (1) yielded the phosphonates (3) with two different alkoxy group efficiently, without the slightest extent of transesterification.

KW - Bridged P-heterocycles

KW - Fragmentation

KW - Phosphonates

KW - Phosphorylation

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U2 - 10.1081/SCC-200036620

DO - 10.1081/SCC-200036620

M3 - Article

VL - 34

SP - 4171

EP - 4178

JO - Synthetic Communications

JF - Synthetic Communications

SN - 0039-7911

IS - 22

ER -