Efficient synthesis of mixed phosphorates by the fragmentation-related phosphorylation of alcohols applying a 2-phosphabicyclo[2.2.2]octa-5,7-diene 2-oxide precursor

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Abstract

The photochemically induced phosphonylation of C1-C4 alcohols by the fragmentation of a P-ethoxy 2-phosphabicyclo[2.2.2]octa-5,7- diene 2-oxide (1) yielded the phosphonates (3) with two different alkoxy group efficiently, without the slightest extent of transesterification.

Original languageEnglish
Pages (from-to)4171-4178
Number of pages8
JournalSynthetic Communications
Volume34
Issue number22
DOIs
Publication statusPublished - Nov 26 2004

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Keywords

  • Bridged P-heterocycles
  • Fragmentation
  • Phosphonates
  • Phosphorylation

ASJC Scopus subject areas

  • Organic Chemistry

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