Efficient method for removal of a carboxylic acid moiety from sterically crowded cyclopropanedicarboxylic acid derivatives

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Abstract

A versatile method was developed to the dealkoxycarbonylation of sterically crowded cyclopropanecarboxylic acid derivatives via a nonhydrolytic ester cleavage followed by a Barton-type decarboxylation.

Original languageEnglish
Pages (from-to)2127-2133
Number of pages7
JournalSynthetic Communications
Volume26
Issue number11
DOIs
Publication statusPublished - Jan 1 1996

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ASJC Scopus subject areas

  • Organic Chemistry

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