Effects of different surfaces on the transport and deposition of ruthenium oxides in high temperature air

N. Vér, L. Matus, A. Pintér, J. Osán, Z. Hózer

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

In order to understand the behaviour of ruthenium oxides in the reactor coolant system during an air ingress accident, new tests were performed in the frame of the RUSET (RUthenium Separate Effect Test) experimental program. These aimed to ascertain the effects of different surfaces (quartz, stainless steel (SS), zirconium alloy, alumina, oxidised metal, and surfaces with Mo or Cs deposits) on the transport and decomposition of ruthenium oxides in air stream along the temperature gradient zone (1100-100 °C). The results demonstrated that the heterogeneous phase decomposition of RuO 3 and RuO 4 to RuO 2 is catalysed more efficiently by the quartz surface than by the SS or alumina surfaces. The presence of MoO 3 layers decreased the RuO x precipitation extent on all investigated surfaces. The trapping effect of Cs deposit on Ru in the temperature gradient zone was proved in the case of the SS surface. On the contrary, presence of Cs precipitate on alumina and especially on quartz surfaces was found to decrease their catalytic effect on the decomposition of ruthenium oxides, and thus increased the RuO 4 concentration in the outlet air. Similarly to the effect observed for Cs deposition, the presence of other fission products in the evaporation area (at 1100 °C) decreased the partial pressure of RuO 4 in the outlet air at the SS surface and increased it at quartz and alumina surfaces. When zirconium (E110) cladding material was placed in the temperature gradient zone, no Ru transmittance occurred until the high temperature end of the zirconium tube was completely oxidised. After the intense oxidation of E110, Ru release occurred only in the presence of other fission product species. Pre-oxidation of SS surfaces in steam had no significant effect on the Ru passage.

Original languageEnglish
Pages (from-to)297-306
Number of pages10
JournalJournal of Nuclear Materials
Volume420
Issue number1-3
DOIs
Publication statusPublished - Jan 2012

Fingerprint

high temperature air
Ruthenium
Oxides
ruthenium
oxides
Stainless Steel
Air
Quartz
Aluminum Oxide
stainless steels
Stainless steel
Alumina
Temperature
quartz
aluminum oxides
Thermal gradients
temperature gradients
fission products
Fission products
air

ASJC Scopus subject areas

  • Nuclear and High Energy Physics
  • Materials Science(all)
  • Nuclear Energy and Engineering

Cite this

Effects of different surfaces on the transport and deposition of ruthenium oxides in high temperature air. / Vér, N.; Matus, L.; Pintér, A.; Osán, J.; Hózer, Z.

In: Journal of Nuclear Materials, Vol. 420, No. 1-3, 01.2012, p. 297-306.

Research output: Contribution to journalArticle

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