Effect of the age of the C60/N-methyl-2-pyrrolidone solution on the structure of clusters in the C60/N-methyl-2-pyrrolidone/water system according to the small-angle neutron scattering data

V. L. Aksenov, M. V. Avdeev, E. A. Kyzyma, L. Rosta, M. V. Korobov

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Abstract

Fullerene clusters in the C60/N-methyl-2-pyrrolidone (NMP)/water system have been investigated by small-angle neutron scattering. It is shown that the scattering cross section corresponding to the size range 10-100 nm depends on the water content in the mixture. Addition of water to a C 60/NMP solution in an amount exceeding 40% leads to a sharp increase in the average scattering cross section. This effect depends on the interval between the times of preparation of a C60/NMP solution and its dilution with water: the size of the clusters formed as a result of adding water increases with increasing the age of the initial solution. The reasons for this effect are discussed.

Original languageEnglish
Pages (from-to)479-482
Number of pages4
JournalCrystallography Reports
Volume52
Issue number3
DOIs
Publication statusPublished - May 1 2007

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ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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