Effect of strongly oxidizing environment on whisker growth form tin coating

Balázs Illés, Barbara Horváth, Gábor Harsányi

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

The effect of a strongly oxidizing environment (105°C/100%RH) on tin whisker formation has been studied with Ni and Ag underlayered samples between the tin surface coating and the bronze base material of the electronic components leads. Using nickel or silver underlayer between the copper substrate and the tin coating can be useful for preventing whiskers. The underlayer blocks the formation of Cu6Sn5 intermetallics which is one of the root causes of whisker growth. The silver underlayered samples started extreme whiskering after 2200h; on the Ni underlayered samples only hillocks have been observed. The shape of the whiskers did not resemble to the usually known whisker appearance. The oxidizing environment creates tin-oxide fast and causes thick layers of SnOx to appear on the surface of the samples and also on the whiskers. This caused the periodic appearance of large amounts of whiskers; but it blocks the length of them. This combined effect results in only large amounts of short whiskers and even causing the thickness of the tin layer to shrink by 80%. The series of tests has also showed that the nickel underlayered samples resisted whiskering better than the silver underlayered samples.

Original languageEnglish
Pages (from-to)2262-2266
Number of pages5
JournalSurface and Coatings Technology
Volume205
Issue number7
DOIs
Publication statusPublished - Dec 25 2010

Fingerprint

Tin
tin
Silver
coatings
Coatings
Nickel
silver
Bronze
Tin oxides
nickel
Intermetallics
Copper
causes
bronzes
tin oxides
intermetallics
Substrates
copper
electronics

Keywords

  • Tin whisker
  • Tin-oxide
  • Underlayer

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Surfaces and Interfaces

Cite this

Effect of strongly oxidizing environment on whisker growth form tin coating. / Illés, Balázs; Horváth, Barbara; Harsányi, Gábor.

In: Surface and Coatings Technology, Vol. 205, No. 7, 25.12.2010, p. 2262-2266.

Research output: Contribution to journalArticle

Illés, Balázs ; Horváth, Barbara ; Harsányi, Gábor. / Effect of strongly oxidizing environment on whisker growth form tin coating. In: Surface and Coatings Technology. 2010 ; Vol. 205, No. 7. pp. 2262-2266.
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