Effect of Ortho Substitution on the Aminolysis of Active Esters in Aprotic Solvents

T. Kőmíves, A. F. Márton, F. Dutka, M. Lów, L. Kisfaludy

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Kinetics of the piperidinolysis of active esters of acetic acid in acetonitrile and chlorobenzene was investigated. The rate data show intramolecular catalysis for the aminolysis of 2-nitro- and 2-cyanophenyl esters, while reactions of 2, 6-disubstituted compounds are hindered by steric inhibition.

Original languageEnglish
Pages (from-to)1359-1360
Number of pages2
JournalZeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume32
Issue number11
DOIs
Publication statusPublished - Nov 1 1977

Fingerprint

Catalysis
Esters
Acetates
Substitution reactions
Kinetics
acetonitrile
chlorobenzene

Keywords

  • Active Ester
  • Aminolysis
  • Aprotic Solvent
  • Kinetics
  • Ortho Effect

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Effect of Ortho Substitution on the Aminolysis of Active Esters in Aprotic Solvents. / Kőmíves, T.; Márton, A. F.; Dutka, F.; Lów, M.; Kisfaludy, L.

In: Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, Vol. 32, No. 11, 01.11.1977, p. 1359-1360.

Research output: Contribution to journalArticle

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AU - Kisfaludy, L.

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