Effect of molecular structure on stereoselectivity during the hydrolysis of diastereoisomeric permethrinic acid esters

Kalmál Simon, Irén Boros, Gyula Balogh, György Hidasi, Elemér Fogassy, Ferenc Faigl, Mária Ács

Research output: Contribution to journalArticle

Abstract

Chemical behaviour and thermal stability differences between the diastereoisomeric cis- and trans-permethrines are elucidated on the basis of their crystal structures. Crystals of the trans-isomer are monoclinic with space group C2/c, with 8 molecules in a unit cell of dimensions a = 38.030(5), b = 9.163(2), c = 11.715(6) Å and B = 105.95(4). Previously published cis-structures are reinvestigated in order to obtain the same accuracy for both derivatives.

Original languageEnglish
Pages (from-to)111-123
Number of pages13
JournalJournal of Molecular Structure
Volume161
Issue numberC
DOIs
Publication statusPublished - Oct 1987

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ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy
  • Organic Chemistry
  • Inorganic Chemistry

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