Effect of hydrogenation under high pressure on the structure and catalytic properties of Cu-Zr amorphous alloys

A. Szummer, M. Janik-Czachor, Á Molnár, I. Marchuk, M. Varga, S. M. Filipek

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Hydrogenation under high pressures up to 3 GPa and at elevated temperatures up to 393 K was used to introduce structural changes in the bulk and on the surface of Cu-Zr amorphous alloys which then were examined by XRD and microscopy. The hydrogenative pre-treatment at a high hydrogen fugacity followed by annealing at 623 K, aimed at desorption of hydrogen, and an eventual exposure of the samples to air at room temperature to oxidize Zr, resulted in a distinct increase of catalytic activity in the dehydrogenation of 2-propanol. A tentative mechanism to account for enhancing the catalytic activity induced by the above combined pre-treatment including correlations between catalytic performance (activity, selectivity) and physical characteristics (morphology, XRD features, Cu(0) specific surface areas) is discussed.

Original languageEnglish
Pages (from-to)205-212
Number of pages8
JournalJournal of Molecular Catalysis A: Chemical
Volume176
Issue number1-2
DOIs
Publication statusPublished - Nov 20 2001

Fingerprint

Amorphous alloys
pretreatment
Hydrogenation
hydrogenation
catalytic activity
Hydrogen
Catalyst activity
2-Propanol
Propanol
hydrogen
Dehydrogenation
dehydrogenation
Specific surface area
Desorption
Microscopic examination
selectivity
desorption
Annealing
microscopy
Temperature

Keywords

  • 2-Propanol
  • Activity enhancement
  • Amorphous alloys
  • Dehydrogenation
  • Hydrogen treatment

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology

Cite this

Effect of hydrogenation under high pressure on the structure and catalytic properties of Cu-Zr amorphous alloys. / Szummer, A.; Janik-Czachor, M.; Molnár, Á; Marchuk, I.; Varga, M.; Filipek, S. M.

In: Journal of Molecular Catalysis A: Chemical, Vol. 176, No. 1-2, 20.11.2001, p. 205-212.

Research output: Contribution to journalArticle

Szummer, A. ; Janik-Czachor, M. ; Molnár, Á ; Marchuk, I. ; Varga, M. ; Filipek, S. M. / Effect of hydrogenation under high pressure on the structure and catalytic properties of Cu-Zr amorphous alloys. In: Journal of Molecular Catalysis A: Chemical. 2001 ; Vol. 176, No. 1-2. pp. 205-212.
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