Abstract
High-field 19F n.m.r. measurements in Me 4NF solutions at 278 K confirm the existence of [AlF i] (3-i)+ complexes for i ≤ 5 but indicate that the widely assumed [A1F 6] 3- does not form at significant concentrations in aqueous solution even at very high F -/Al III ratios.
| Original language | English |
|---|---|
| Pages (from-to) | 625-626 |
| Number of pages | 2 |
| Journal | Australian Journal of Chemistry |
| Volume | 53 |
| Issue number | 7 |
| Publication status | Published - Dec 1 2000 |
Keywords
- Aluminium(III)
- Complexes
- Fluoride
- Fluorine-19 n.m.r
- Stepwise equilibrium constants
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Hefter, G., Odor, A. B., & Tóth, I. (2000). Does [A1F 6] 3- exist in aqueous solution? Australian Journal of Chemistry, 53(7), 625-626.