Does [A1F 6] 3- exist in aqueous solution?

Glenn Hefter, Andrea B. Odor, Imre Tóth

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

High-field 19F n.m.r. measurements in Me 4NF solutions at 278 K confirm the existence of [AlF i] (3-i)+ complexes for i ≤ 5 but indicate that the widely assumed [A1F 6] 3- does not form at significant concentrations in aqueous solution even at very high F -/Al III ratios.

Original languageEnglish
Pages (from-to)625-626
Number of pages2
JournalAustralian Journal of Chemistry
Volume53
Issue number7
Publication statusPublished - Dec 1 2000

Keywords

  • Aluminium(III)
  • Complexes
  • Fluoride
  • Fluorine-19 n.m.r
  • Stepwise equilibrium constants

ASJC Scopus subject areas

  • Chemistry(all)

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