Direct signature of light-induced conical intersections in diatomics

G. J. Halász, Vibók, L. S. Cederbaum

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48 Citations (Scopus)

Abstract

Nonadiabatic effects are ubiquitous in physics, chemistry, and biology. They are strongly amplified by conical intersections (CIs), which are degeneracies between electronic states of triatomic or larger molecules. A few years ago it was revealed that CIs in molecular systems can be formed by laser light, even in diatomics. Because of the prevailing strong nonadiabatic couplings, the existence of such laser-induced conical intersections (LICIs) may considerably change the dynamical behavior of molecular systems. By analyzing the photodissociation process of the D2+ molecule carefully, we found a robust effect in the angular distribution of the photofragments that serves as a direct signature of the LICI, providing undoubted evidence of its existence. (Figure Presented).

Original languageEnglish
Pages (from-to)348-354
Number of pages7
JournalJournal of Physical Chemistry Letters
Volume6
Issue number3
DOIs
Publication statusPublished - Feb 5 2015

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ASJC Scopus subject areas

  • Materials Science(all)
  • Physical and Theoretical Chemistry

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