Direct kinetic parameters for the reaction of Br atoms with neopentane

Research output: Contribution to journalArticle

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Abstract

Laser flash photolysis coupled with resonance fluorescence detection of Br atoms was used to investigate the temperature dependence of the reaction Br + neo-C5H12 (1) between 688 and 775 K. The standard enthalpy of formation for the neo-C5H11 radical was estimated to be 34.7 and 41.6 kJ mol-1, depending on the value of the activation energy assumed for the reverse reaction neo-C5H11+HBr(-1).

Original languageEnglish
Pages (from-to)49-55
Number of pages7
JournalInternational Journal of Chemical Kinetics
Volume33
Issue number1
DOIs
Publication statusPublished - Jan 2001

Fingerprint

neopentane
Photolysis
Kinetic parameters
Enthalpy
Lasers
Activation energy
Fluorescence
Atoms
Temperature
kinetics
resonance fluorescence
atoms
flash
photolysis
enthalpy
activation energy
temperature dependence
lasers

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Catalysis

Cite this

Direct kinetic parameters for the reaction of Br atoms with neopentane. / Imrik, K.; Dóbé, S.; Bérces, T.

In: International Journal of Chemical Kinetics, Vol. 33, No. 1, 01.2001, p. 49-55.

Research output: Contribution to journalArticle

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