Laser flash photolysis coupled with resonance fluorescence detection of Br atoms was used to investigate the temperature dependence of the reaction Br + neo-C5H12 (1) between 688 and 775 K. The standard enthalpy of formation for the neo-C5H11 radical was estimated to be 34.7 and 41.6 kJ mol-1, depending on the value of the activation energy assumed for the reverse reaction neo-C5H11+HBr(-1).
|Number of pages||7|
|Journal||International Journal of Chemical Kinetics|
|Publication status||Published - Jan 1 2001|
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry