Diphosphetes - Substituent stabilized ring systems

Guy Bertrand, Wolfgang Eisfeld, László Nyulászi, Regis Reau, Manfred Regitz, Dénes Szieberth

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The mechanism of the formation of σ2P, σ4P-1,2-diphosphetes from phosphaacetylene and phosphinocarbene has been explored by quantum chemical methods. A stepwise mechanism has been established, and no transition state for a concerted pathway could be obtained. The electron distribution of the ring can be understood in terms of a MO model, where the two substituents at phosphorus act as a pseudo π center. Amino substituents on the σ4 phosphorus and silyl group on the neighbouring carbon change the stability order of the possible isomers, stabilizing the 1,2-diphosphete ring. Substitution at the σ2P-by increasing its valence-destabilizes the diphosphete ring, which remains stable only as a result of the amino and silyl substituents.

Original languageEnglish
Pages (from-to)2324-2327
Number of pages4
JournalJournal of the Chemical Society. Perkin Transactions 2
Issue number11
Publication statusPublished - Nov 1 2000

    Fingerprint

ASJC Scopus subject areas

  • Chemistry(all)

Cite this