Dichloridobis(2-methoxy-dibenzo[c,e][1,2]oxaphospho-rine-P)platinum(II) trichloro-methane solvate

Tamás Holczbauer, G. Keglevich, Andrea Kerényi, M. Czugler

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The title compound, [PtCl2(C13H11O 2P)2]·CHCl3, has a rare PtCl2 bridging of two dibenzooxaphospho-rine ligands through the metal atom. The Pt II ion is in a slightly distorted square-planar environment. The trichloro-methane solvent mol-ecule shows rotational disorder (major occupancy is 0.75) and is placed near to the inversion centre at (1/2, 1/2, 0) in channels parallel to the a axis. The solvent mol-ecule is linked to the complex mol-ecule via inter-molecular bifurcated C - H⋯Cl and C - H⋯O hydrogen bonds. The crystal structure is further stabilized by π-π inter-actions involving the benzene rings, with a centroid-centroid distance of 3.658 (8) Å.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number3
DOIs
Publication statusPublished - 2009

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Chloroform
Platinum
centroids
Methane
platinum
methane
Benzene
Hydrogen bonds
Crystal structure
Metals
Ligands
benzene
disorders
Ions
inversions
hydrogen bonds
Atoms
ligands
crystal structure
rings

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

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title = "Dichloridobis(2-methoxy-dibenzo[c,e][1,2]oxaphospho-rine-P)platinum(II) trichloro-methane solvate",
abstract = "The title compound, [PtCl2(C13H11O 2P)2]·CHCl3, has a rare PtCl2 bridging of two dibenzooxaphospho-rine ligands through the metal atom. The Pt II ion is in a slightly distorted square-planar environment. The trichloro-methane solvent mol-ecule shows rotational disorder (major occupancy is 0.75) and is placed near to the inversion centre at (1/2, 1/2, 0) in channels parallel to the a axis. The solvent mol-ecule is linked to the complex mol-ecule via inter-molecular bifurcated C - H⋯Cl and C - H⋯O hydrogen bonds. The crystal structure is further stabilized by π-π inter-actions involving the benzene rings, with a centroid-centroid distance of 3.658 (8) {\AA}.",
author = "Tam{\'a}s Holczbauer and G. Keglevich and Andrea Ker{\'e}nyi and M. Czugler",
year = "2009",
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language = "English",
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journal = "Acta Crystallographica Section E: Structure Reports Online",
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publisher = "International Union of Crystallography",
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TY - JOUR

T1 - Dichloridobis(2-methoxy-dibenzo[c,e][1,2]oxaphospho-rine-P)platinum(II) trichloro-methane solvate

AU - Holczbauer, Tamás

AU - Keglevich, G.

AU - Kerényi, Andrea

AU - Czugler, M.

PY - 2009

Y1 - 2009

N2 - The title compound, [PtCl2(C13H11O 2P)2]·CHCl3, has a rare PtCl2 bridging of two dibenzooxaphospho-rine ligands through the metal atom. The Pt II ion is in a slightly distorted square-planar environment. The trichloro-methane solvent mol-ecule shows rotational disorder (major occupancy is 0.75) and is placed near to the inversion centre at (1/2, 1/2, 0) in channels parallel to the a axis. The solvent mol-ecule is linked to the complex mol-ecule via inter-molecular bifurcated C - H⋯Cl and C - H⋯O hydrogen bonds. The crystal structure is further stabilized by π-π inter-actions involving the benzene rings, with a centroid-centroid distance of 3.658 (8) Å.

AB - The title compound, [PtCl2(C13H11O 2P)2]·CHCl3, has a rare PtCl2 bridging of two dibenzooxaphospho-rine ligands through the metal atom. The Pt II ion is in a slightly distorted square-planar environment. The trichloro-methane solvent mol-ecule shows rotational disorder (major occupancy is 0.75) and is placed near to the inversion centre at (1/2, 1/2, 0) in channels parallel to the a axis. The solvent mol-ecule is linked to the complex mol-ecule via inter-molecular bifurcated C - H⋯Cl and C - H⋯O hydrogen bonds. The crystal structure is further stabilized by π-π inter-actions involving the benzene rings, with a centroid-centroid distance of 3.658 (8) Å.

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