Dibenzophosphapentaphenes: Exploiting P chemistry for gap fine-tuning and coordination-driven assembly of planar polycyclic aromatic hydrocarbons

Pierre Antoine Bouit, Aude Escande, Rózsa Szücs, D. Szieberth, Christophe Lescop, L. Nyulászi, Muriel Hissler, Régis Réau

Research output: Contribution to journalArticle

88 Citations (Scopus)

Abstract

A synthetic route to planar P-modified polycylic aromatic hydrocarbons (PAHs) is described. The presence of a reactive σ 3, λ 3-P moiety within the sp 2-carbon scaffold allows the preparation of a new family of PAHs displaying tunable optical and redox properties. Their frontier molecular orbitals (MOs) are derived from the corresponding phosphole MOs and show extended conjugation with the entire π framework. The coordination ability of the P center allows the coordination-driven assembly of two molecular PAHs onto a Au I ion.

Original languageEnglish
Pages (from-to)6524-6527
Number of pages4
JournalJournal of the American Chemical Society
Volume134
Issue number15
DOIs
Publication statusPublished - Apr 18 2012

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Aromatic Hydrocarbons
Aromatic hydrocarbons
Polycyclic Aromatic Hydrocarbons
Polycyclic aromatic hydrocarbons
Tuning
Molecular orbitals
Scaffolds
Oxidation-Reduction
Carbon
Ions

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Dibenzophosphapentaphenes : Exploiting P chemistry for gap fine-tuning and coordination-driven assembly of planar polycyclic aromatic hydrocarbons. / Bouit, Pierre Antoine; Escande, Aude; Szücs, Rózsa; Szieberth, D.; Lescop, Christophe; Nyulászi, L.; Hissler, Muriel; Réau, Régis.

In: Journal of the American Chemical Society, Vol. 134, No. 15, 18.04.2012, p. 6524-6527.

Research output: Contribution to journalArticle

Bouit, Pierre Antoine ; Escande, Aude ; Szücs, Rózsa ; Szieberth, D. ; Lescop, Christophe ; Nyulászi, L. ; Hissler, Muriel ; Réau, Régis. / Dibenzophosphapentaphenes : Exploiting P chemistry for gap fine-tuning and coordination-driven assembly of planar polycyclic aromatic hydrocarbons. In: Journal of the American Chemical Society. 2012 ; Vol. 134, No. 15. pp. 6524-6527.
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