Determination of the initiation rates in the liquid Phase Oxidation of Ethylbenzene

T. Vidóczy, Dezso Gal

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The rate of initiation during the oxidation of ethylbenzene has been determined at various conversions both at 120 as well as 129°C.In order to complete the determination the reactivities of the inhibitors α - and β -naphthol, 2,6-di-tert.-butyl-phenol, N-phenyl-²-naphthylamine,'-diphenyl-para-phenylene-diamine toward oxygen and the products of the oxidation of ethylbenzene have been thoroughly studied and the most suitable ones were applied in the varying conversion ranges. By the use of the initiation rates measured with the help of the corresponding inhibitors the upper limits of the rate constants of processes yielding free radicals have been estimated.

Original languageEnglish
Pages (from-to)179-186
Number of pages8
JournalZeitschrift fur Physikalische Chemie
Volume109
Issue number2
DOIs
Publication statusPublished - 1978

Fingerprint

liquid phases
Oxidation
inhibitors
oxidation
Diamines
Liquids
Phenol
Free Radicals
Rate constants
diamines
Oxygen
phenols
free radicals
reactivity
oxygen
products
ethylbenzene
diphenyl
2-naphthol

Keywords

  • Ethylbenzene oxidation
  • Inhibitor method

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Determination of the initiation rates in the liquid Phase Oxidation of Ethylbenzene. / Vidóczy, T.; Gal, Dezso.

In: Zeitschrift fur Physikalische Chemie, Vol. 109, No. 2, 1978, p. 179-186.

Research output: Contribution to journalArticle

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