Description of the rate of heterogeneous chemical reactions

Gy Pokol, S. Gál, E. Pungor

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Theoretical studies using the dα dt = k(T)f(α) rate equation for heterogeneous processes - especially those involving at least one solid reactant - are reported. Dependence of k on the sample size is shown in general. Possible rate expressions for reversible systems are discussed. New forms analogous to physical fluxes and current densities are presented for the kinetic description of the chemical step of the processes concerned.

Original languageEnglish
Pages (from-to)259-265
Number of pages7
JournalThermochimica Acta
Volume33
Issue numberC
DOIs
Publication statusPublished - Oct 1979

ASJC Scopus subject areas

  • Instrumentation
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

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