Demethylation of the [Me3Sn(PhN2O2)] 4 tetramer into dimeric [Me2Sn(PhN2O 2)2]2: A thermally induced methyl-transfer between supramolecules

Andrea Deák, G. Tárkányi

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The single crystals of tetrameric [Me3Sn(PhN2O 2)]4 (1) supramolecule demethylates into single crystals of [Me2Sn(PbN2O2)2]2 dimer (2) and volatile Me4Sn, as a result of a crystal-to-crystal supramolecular structural transformation, which occurs upon heating and it is accompanied by a significant change of the molecular and crystal structures.

Original languageEnglish
Pages (from-to)4074-4076
Number of pages3
JournalChemical Communications
Issue number32
DOIs
Publication statusPublished - Aug 28 2005

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Single crystals
Crystals
Dimers
Molecular structure
Crystal structure
Heating

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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abstract = "The single crystals of tetrameric [Me3Sn(PhN2O 2)]4 (1) supramolecule demethylates into single crystals of [Me2Sn(PbN2O2)2]2 dimer (2) and volatile Me4Sn, as a result of a crystal-to-crystal supramolecular structural transformation, which occurs upon heating and it is accompanied by a significant change of the molecular and crystal structures.",
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AB - The single crystals of tetrameric [Me3Sn(PhN2O 2)]4 (1) supramolecule demethylates into single crystals of [Me2Sn(PbN2O2)2]2 dimer (2) and volatile Me4Sn, as a result of a crystal-to-crystal supramolecular structural transformation, which occurs upon heating and it is accompanied by a significant change of the molecular and crystal structures.

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