Decomposition of nitrous oxide on some doped cupric oxide catalysts

I. Batta, F. Solymosi, Z. G. Szabó

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The decomposition of nitrous oxide on pure and doped cupric oxide with ions of lower and higher valency was studied in detail. The heat treatment of cupric oxide between 550-800 °C resulted in about 14 kcal increase of the activation energy. The building-in of ions of higher valency increased to a marked extent the activation energy, whereas the incorporation of lower valency ions decreased the activation energy to a lesser extent. According to the present conductivity measurements, cupric oxide-in contrast with earlier observations-proved to be a defect conductor. The kinetics of the decomposition of N2O can be interpreted on the basis of this type of conductivity.

Original languageEnglish
Pages (from-to)103-112
Number of pages10
JournalJournal of Catalysis
Volume1
Issue number2
DOIs
Publication statusPublished - May 1962

    Fingerprint

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

Cite this