Cyclic bis(phosphanyl)carbenium ion by protonation of a 1,3-diphosphacyclobutane-2,4-diyl

Manuel Sebastian, Aaron Hoskin, Martin Nieger, L. Nyulászi, Edgar Niecke

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

Strong interactions with the lone pairs of the neighboring, pyramidalized phosphorus atoms stabilize the cyclic carbenium ion 2. The 1,3-bis(phosphanyl) carbenium unit was obtained by protonation of a 1,3-diphosphacyclobutane-2,4- dlyl 1 (R = 2,4,6-tBU3C6H2, HX = trifluoromethanesulfonic acid).

Original languageEnglish
Pages (from-to)1405-1408
Number of pages4
JournalAngewandte Chemie - International Edition
Volume44
Issue number9
DOIs
Publication statusPublished - Feb 18 2005

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Protonation
Phosphorus
Ions
Atoms
Acids
trifluoromethanesulfonic acid

Keywords

  • Ab initio calculations
  • Carbenium ions
  • Carbocations
  • Diradicals
  • Phosphorus heterocycles

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Cyclic bis(phosphanyl)carbenium ion by protonation of a 1,3-diphosphacyclobutane-2,4-diyl. / Sebastian, Manuel; Hoskin, Aaron; Nieger, Martin; Nyulászi, L.; Niecke, Edgar.

In: Angewandte Chemie - International Edition, Vol. 44, No. 9, 18.02.2005, p. 1405-1408.

Research output: Contribution to journalArticle

Sebastian, Manuel ; Hoskin, Aaron ; Nieger, Martin ; Nyulászi, L. ; Niecke, Edgar. / Cyclic bis(phosphanyl)carbenium ion by protonation of a 1,3-diphosphacyclobutane-2,4-diyl. In: Angewandte Chemie - International Edition. 2005 ; Vol. 44, No. 9. pp. 1405-1408.
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