Cyanide-bridged bimetallic multidimensional structures derived from organotin(IV) and dicyanoaurate building blocks: ION exchange, luminescence, and gas sorption properties

Andrea Deák, Tünde Tunyogi, Csaba Jobbágy, Zoltán Károly, P. Baranyai, G. Pálinkás

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The recent success of using methyltin(IV) cations in constructing multidimensional structures containing the Au-CN-Sn link with interesting physical properties will be surveyed. The methyltin(IV)-dicyanoaurates, Me 3Sn[Au (CN) 2] (1) and Me 2Sn[Au(CN) 2] 2 (2) containing the Au- CN-Sn link can be easily prepared by aqueous reaction of Me 3SnCl or Me 2SnCl 2 with stoichiometric amounts of an aqueous solution of K[Au(CN) 2]. The room temperature solid-state emission spectrum of 1 excited at 254 nm shows two intense emission bands at 442 and 670 nm, and a shoulder at 390 nm. When excited at 320 nm, the crystalline sample shows two intense emission bands at 442 and 720 nm, and a shoulder at 380 nm. After 2 min of grinding, only the blue emission band at 442 nm is observed. In contrast, the emission spectrum of 2 shows only one emission maximum at 422 nm. The porosity of 1 and 2 was probed by gas sorption measurements performed at 77 K. 1 exhibited no detectable microporosity as revealed by the inspection of the N 2, H 2, as well as, O 2 isotherms. The gas adsorption studies reveal that only a small amount of N 2 and H 2 (3.82 and 4.66 cm 3 g ?1, respectively) is adsorbed by the framework of 2 at 77 K. However, a CO uptake of 11.20 cm 3 g ?1 can be reached at 1 atm. The framework of 2 can take up significant amounts of O 2 (23.27 cm 3 g ?1). In addition to intriguing photoluminescence and gas sorption behavior, these complexes also exhibit ion exchange properties in the presence of bivalent transition metal cations, such as cobalt(II), nickel(II), copper(II), and zinc(II)

Original languageEnglish
Pages (from-to)35-41
Number of pages7
JournalGold Bulletin
Volume45
Issue number1
DOIs
Publication statusPublished - Mar 2012

Fingerprint

gold cyanide
Cyanides
Cations
Sorption
Luminescence
Gases
Positive ions
Microporosity
Gas adsorption
Carbon Monoxide
Cobalt
Nickel
Transition metals
Isotherms
Zinc
Copper
Ion exchange
Photoluminescence
Physical properties
Porosity

Keywords

  • Dicyanoaurate
  • Gas sorption
  • Ion exchange
  • Organotin(IV)-dicyanoaurates
  • Photoluminescence

ASJC Scopus subject areas

  • Materials Science(all)
  • Inorganic Chemistry

Cite this

Cyanide-bridged bimetallic multidimensional structures derived from organotin(IV) and dicyanoaurate building blocks : ION exchange, luminescence, and gas sorption properties. / Deák, Andrea; Tunyogi, Tünde; Jobbágy, Csaba; Károly, Zoltán; Baranyai, P.; Pálinkás, G.

In: Gold Bulletin, Vol. 45, No. 1, 03.2012, p. 35-41.

Research output: Contribution to journalArticle

@article{2b0976d0f0d24f5e93a221d6717d7583,
title = "Cyanide-bridged bimetallic multidimensional structures derived from organotin(IV) and dicyanoaurate building blocks: ION exchange, luminescence, and gas sorption properties",
abstract = "The recent success of using methyltin(IV) cations in constructing multidimensional structures containing the Au-CN-Sn link with interesting physical properties will be surveyed. The methyltin(IV)-dicyanoaurates, Me 3Sn[Au (CN) 2] (1) and Me 2Sn[Au(CN) 2] 2 (2) containing the Au- CN-Sn link can be easily prepared by aqueous reaction of Me 3SnCl or Me 2SnCl 2 with stoichiometric amounts of an aqueous solution of K[Au(CN) 2]. The room temperature solid-state emission spectrum of 1 excited at 254 nm shows two intense emission bands at 442 and 670 nm, and a shoulder at 390 nm. When excited at 320 nm, the crystalline sample shows two intense emission bands at 442 and 720 nm, and a shoulder at 380 nm. After 2 min of grinding, only the blue emission band at 442 nm is observed. In contrast, the emission spectrum of 2 shows only one emission maximum at 422 nm. The porosity of 1 and 2 was probed by gas sorption measurements performed at 77 K. 1 exhibited no detectable microporosity as revealed by the inspection of the N 2, H 2, as well as, O 2 isotherms. The gas adsorption studies reveal that only a small amount of N 2 and H 2 (3.82 and 4.66 cm 3 g ?1, respectively) is adsorbed by the framework of 2 at 77 K. However, a CO uptake of 11.20 cm 3 g ?1 can be reached at 1 atm. The framework of 2 can take up significant amounts of O 2 (23.27 cm 3 g ?1). In addition to intriguing photoluminescence and gas sorption behavior, these complexes also exhibit ion exchange properties in the presence of bivalent transition metal cations, such as cobalt(II), nickel(II), copper(II), and zinc(II)",
keywords = "Dicyanoaurate, Gas sorption, Ion exchange, Organotin(IV)-dicyanoaurates, Photoluminescence",
author = "Andrea De{\'a}k and T{\"u}nde Tunyogi and Csaba Jobb{\'a}gy and Zolt{\'a}n K{\'a}roly and P. Baranyai and G. P{\'a}link{\'a}s",
year = "2012",
month = "3",
doi = "10.1007/s13404-012-0041-1",
language = "English",
volume = "45",
pages = "35--41",
journal = "Gold Bulletin",
issn = "0017-1557",
publisher = "Springer Berlin",
number = "1",

}

TY - JOUR

T1 - Cyanide-bridged bimetallic multidimensional structures derived from organotin(IV) and dicyanoaurate building blocks

T2 - ION exchange, luminescence, and gas sorption properties

AU - Deák, Andrea

AU - Tunyogi, Tünde

AU - Jobbágy, Csaba

AU - Károly, Zoltán

AU - Baranyai, P.

AU - Pálinkás, G.

PY - 2012/3

Y1 - 2012/3

N2 - The recent success of using methyltin(IV) cations in constructing multidimensional structures containing the Au-CN-Sn link with interesting physical properties will be surveyed. The methyltin(IV)-dicyanoaurates, Me 3Sn[Au (CN) 2] (1) and Me 2Sn[Au(CN) 2] 2 (2) containing the Au- CN-Sn link can be easily prepared by aqueous reaction of Me 3SnCl or Me 2SnCl 2 with stoichiometric amounts of an aqueous solution of K[Au(CN) 2]. The room temperature solid-state emission spectrum of 1 excited at 254 nm shows two intense emission bands at 442 and 670 nm, and a shoulder at 390 nm. When excited at 320 nm, the crystalline sample shows two intense emission bands at 442 and 720 nm, and a shoulder at 380 nm. After 2 min of grinding, only the blue emission band at 442 nm is observed. In contrast, the emission spectrum of 2 shows only one emission maximum at 422 nm. The porosity of 1 and 2 was probed by gas sorption measurements performed at 77 K. 1 exhibited no detectable microporosity as revealed by the inspection of the N 2, H 2, as well as, O 2 isotherms. The gas adsorption studies reveal that only a small amount of N 2 and H 2 (3.82 and 4.66 cm 3 g ?1, respectively) is adsorbed by the framework of 2 at 77 K. However, a CO uptake of 11.20 cm 3 g ?1 can be reached at 1 atm. The framework of 2 can take up significant amounts of O 2 (23.27 cm 3 g ?1). In addition to intriguing photoluminescence and gas sorption behavior, these complexes also exhibit ion exchange properties in the presence of bivalent transition metal cations, such as cobalt(II), nickel(II), copper(II), and zinc(II)

AB - The recent success of using methyltin(IV) cations in constructing multidimensional structures containing the Au-CN-Sn link with interesting physical properties will be surveyed. The methyltin(IV)-dicyanoaurates, Me 3Sn[Au (CN) 2] (1) and Me 2Sn[Au(CN) 2] 2 (2) containing the Au- CN-Sn link can be easily prepared by aqueous reaction of Me 3SnCl or Me 2SnCl 2 with stoichiometric amounts of an aqueous solution of K[Au(CN) 2]. The room temperature solid-state emission spectrum of 1 excited at 254 nm shows two intense emission bands at 442 and 670 nm, and a shoulder at 390 nm. When excited at 320 nm, the crystalline sample shows two intense emission bands at 442 and 720 nm, and a shoulder at 380 nm. After 2 min of grinding, only the blue emission band at 442 nm is observed. In contrast, the emission spectrum of 2 shows only one emission maximum at 422 nm. The porosity of 1 and 2 was probed by gas sorption measurements performed at 77 K. 1 exhibited no detectable microporosity as revealed by the inspection of the N 2, H 2, as well as, O 2 isotherms. The gas adsorption studies reveal that only a small amount of N 2 and H 2 (3.82 and 4.66 cm 3 g ?1, respectively) is adsorbed by the framework of 2 at 77 K. However, a CO uptake of 11.20 cm 3 g ?1 can be reached at 1 atm. The framework of 2 can take up significant amounts of O 2 (23.27 cm 3 g ?1). In addition to intriguing photoluminescence and gas sorption behavior, these complexes also exhibit ion exchange properties in the presence of bivalent transition metal cations, such as cobalt(II), nickel(II), copper(II), and zinc(II)

KW - Dicyanoaurate

KW - Gas sorption

KW - Ion exchange

KW - Organotin(IV)-dicyanoaurates

KW - Photoluminescence

UR - http://www.scopus.com/inward/record.url?scp=84862639915&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84862639915&partnerID=8YFLogxK

U2 - 10.1007/s13404-012-0041-1

DO - 10.1007/s13404-012-0041-1

M3 - Article

AN - SCOPUS:84862639915

VL - 45

SP - 35

EP - 41

JO - Gold Bulletin

JF - Gold Bulletin

SN - 0017-1557

IS - 1

ER -