Crystal structure of diethyl 2-acetoxy-2-[3-(4-nitrophenyl)-3-oxo-1-phenylpropyl]malonate

Nora Veronika May, Gyula TamasGal, Zsolt Rapib, P. Bakó

Research output: Contribution to journalArticle

Abstract

In the racemic title compound, C24H25NO9, the dihedral angle between the planes of the two benzene-ring systems is 80.16 (6)°, while the side-chain conformation is stabilized by a methylene-carboxyl C-H. O hydrogen bond. Weak intermolecular C-H. O hydrogen bonds form inversion dimers [graph set R2 2(16)] which are linked into chains extending along a. Further C-H. O hydrogen bonding extends the structure along b through cyclic R2 2(10) motifs. Although no π-π aromatic ring interactions are present in the structure, C-H.π ring interactions across c generate an overall three-dimensional supramolecular structure.

Original languageEnglish
Pages (from-to)257-260
Number of pages4
JournalActa Crystallographica Section E: Crystallographic Communications
Volume72
Issue number2
DOIs
Publication statusPublished - Feb 1 2016

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Keywords

  • C-H.π ring interactions
  • crown ether catalyst
  • Crystal structure
  • hydrogen bonding
  • phase-transfer reaction
  • phenylpropyl malonate

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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