CO2 reforming of CH4 on doped Rh/Al2O 3 catalysts

I. Sarusi, K. Fodor, K. Baán, A. Oszkó, G. Pótári, A. Erdóhelyi

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

The reforming of methane with carbon dioxide has been investigated at 773 K on Rh/Al2O3 promoted with TiO2 and V 2O5. In addition, the dissociation of carbon dioxide and methane has also been examined. TPR and XPS results revealed that during the pre-treatment of the catalysts not only Rh reduced but also TiO2 slightly and V2O5 significantly to V4+ below 600 K. The dissociation of carbon dioxide occurred most easily on vanadia promoted catalyst. Vanadia and titania promoted Rh/Al2O3 was found to be more active in the CO2 + CH4 reaction than the Rh/Al2O3. The increase of the conversion observed on V2O5 and TiO2 promoted Rh/Al2O 3 catalysts could be attributed to the oxygen vacancies which formed on the additives during the pretreatment and the reaction.

Original languageEnglish
Pages (from-to)132-139
Number of pages8
JournalCatalysis Today
Volume171
Issue number1
DOIs
Publication statusPublished - Aug 10 2011

Fingerprint

Reforming reactions
Carbon Dioxide
Carbon dioxide
Methane
Catalysts
Oxygen vacancies
X ray photoelectron spectroscopy
Titanium
vanadium pentoxide

Keywords

  • Dissociation of carbon dioxide
  • Dry reforming of methane
  • Promoted alumina supported Rh catalyst
  • Reaction of methane with carbon dioxide

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

CO2 reforming of CH4 on doped Rh/Al2O 3 catalysts. / Sarusi, I.; Fodor, K.; Baán, K.; Oszkó, A.; Pótári, G.; Erdóhelyi, A.

In: Catalysis Today, Vol. 171, No. 1, 10.08.2011, p. 132-139.

Research output: Contribution to journalArticle

Sarusi, I. ; Fodor, K. ; Baán, K. ; Oszkó, A. ; Pótári, G. ; Erdóhelyi, A. / CO2 reforming of CH4 on doped Rh/Al2O 3 catalysts. In: Catalysis Today. 2011 ; Vol. 171, No. 1. pp. 132-139.
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