Corrosion protection properties of hydroxamic acid self-assembled monolayer on carbon steel

Abdulmajed Alagta, I. Felhősi, I. Bertóti, E. Kálmán

Research output: Contribution to journalArticle

65 Citations (Scopus)

Abstract

Self assembled monolayers (SAMs) of hydroxamic acids CH3(CH2)nCONHOH with different alkyl length were formed on the carbon steel electrode surface. The corrosion protection properties of the monolayers were examined and characterized by electrochemical polarization curves, electrochemical impedance spectroscopy, X-ray photoelectron spectroscopy (XPS) and contact angle measurements. XPS results showed that the hydroxamic acid molecules adsorbed on the carbon steel surface, and the contact angle values on the modified surface supported the formation of hydrophobic hydroxamic acid SAMs. The results of electrochemical studies showed that the values of the corrosion potential shift towards the positive direction, and anodic currents of the carbon steel dissolution significantly decreases, indicating that hydroxamic acids are anodic inhibitors. However, the chain length and assembling time influence the protection efficiency.

Original languageEnglish
Pages (from-to)1644-1649
Number of pages6
JournalCorrosion Science
Volume50
Issue number6
DOIs
Publication statusPublished - Jun 2008

Fingerprint

Hydroxamic Acids
Corrosion protection
Self assembled monolayers
Carbon steel
Acids
Contact angle
X ray photoelectron spectroscopy
Angle measurement
Electrochemical impedance spectroscopy
Chain length
Monolayers
Dissolution
Polarization
Corrosion
Electrodes
Molecules

Keywords

  • A. Hydroxamic acid
  • B. EIS
  • B. XPS
  • C. Inhibition in neutral solutions
  • C. SAMs

ASJC Scopus subject areas

  • Materials Science(all)
  • Metals and Alloys

Cite this

Corrosion protection properties of hydroxamic acid self-assembled monolayer on carbon steel. / Alagta, Abdulmajed; Felhősi, I.; Bertóti, I.; Kálmán, E.

In: Corrosion Science, Vol. 50, No. 6, 06.2008, p. 1644-1649.

Research output: Contribution to journalArticle

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AU - Bertóti, I.

AU - Kálmán, E.

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N2 - Self assembled monolayers (SAMs) of hydroxamic acids CH3(CH2)nCONHOH with different alkyl length were formed on the carbon steel electrode surface. The corrosion protection properties of the monolayers were examined and characterized by electrochemical polarization curves, electrochemical impedance spectroscopy, X-ray photoelectron spectroscopy (XPS) and contact angle measurements. XPS results showed that the hydroxamic acid molecules adsorbed on the carbon steel surface, and the contact angle values on the modified surface supported the formation of hydrophobic hydroxamic acid SAMs. The results of electrochemical studies showed that the values of the corrosion potential shift towards the positive direction, and anodic currents of the carbon steel dissolution significantly decreases, indicating that hydroxamic acids are anodic inhibitors. However, the chain length and assembling time influence the protection efficiency.

AB - Self assembled monolayers (SAMs) of hydroxamic acids CH3(CH2)nCONHOH with different alkyl length were formed on the carbon steel electrode surface. The corrosion protection properties of the monolayers were examined and characterized by electrochemical polarization curves, electrochemical impedance spectroscopy, X-ray photoelectron spectroscopy (XPS) and contact angle measurements. XPS results showed that the hydroxamic acid molecules adsorbed on the carbon steel surface, and the contact angle values on the modified surface supported the formation of hydrophobic hydroxamic acid SAMs. The results of electrochemical studies showed that the values of the corrosion potential shift towards the positive direction, and anodic currents of the carbon steel dissolution significantly decreases, indicating that hydroxamic acids are anodic inhibitors. However, the chain length and assembling time influence the protection efficiency.

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