Correlation between structural and electrical properties of heavily lithiated boron oxide solid electrolytes

E. E. Horopanitis, G. Perentzis, A. Beck, L. Guczi, G. Peto, L. Papadimitriou

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Infrared and impedance measurements have been carried out on high lithium content boron oxide solid electrolytes xLi2O-B2O3, with x = 3.0-4.5, in order to establish the correlation between their structural and electrical properties. The samples are two-phase materials, in which crystalline islands are scattered throughout the vitreous background phase. The evolution of structural and electrical properties with increasing x exhibits a marked differentiation around x = 4.0, which is associated with increasing crystallization in the material.

Original languageEnglish
Pages (from-to)374-379
Number of pages6
JournalJournal of Non-Crystalline Solids
Volume354
Issue number2-9
DOIs
Publication statusPublished - Jan 15 2008

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Keywords

  • Borates
  • FTIR measurements
  • Fast ion conduction
  • Glass transition

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Materials Chemistry

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