Correlating electronic and catalytic properties of frustrated Lewis pairs for imine hydrogenation

Éva Dorkó, Bianka Kótai, Tamás Földes, Ádám Gyömöre, I. Pápai, T. Soós

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Combined computational and experimental work to probe Lewis acidity of some boranes to be used in FLP hydrogenation. Gutmann-Beckett method of estimating Lewis acidity has limited capacity for sterically congested boranes. Calculated hydride affinity is a more appropriate tool for gauging Lewis acidity and correlate their FLP hydrogenation utility.

Original languageEnglish
Pages (from-to)258-262
Number of pages5
JournalJournal of Organometallic Chemistry
Volume847
DOIs
Publication statusPublished - Jan 1 2017

Fingerprint

Boranes
Imines
Hydrogenation
Acidity
acidity
imines
hydrogenation
boranes
electronics
Gaging
Hydrides
hydrides
affinity
estimating
probes

Keywords

  • Catalysis
  • DFT
  • Frustrated Lewis pairs
  • Hydrogenation
  • Lewis acidity

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Correlating electronic and catalytic properties of frustrated Lewis pairs for imine hydrogenation. / Dorkó, Éva; Kótai, Bianka; Földes, Tamás; Gyömöre, Ádám; Pápai, I.; Soós, T.

In: Journal of Organometallic Chemistry, Vol. 847, 01.01.2017, p. 258-262.

Research output: Contribution to journalArticle

Dorkó, Éva ; Kótai, Bianka ; Földes, Tamás ; Gyömöre, Ádám ; Pápai, I. ; Soós, T. / Correlating electronic and catalytic properties of frustrated Lewis pairs for imine hydrogenation. In: Journal of Organometallic Chemistry. 2017 ; Vol. 847. pp. 258-262.
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