Copper-Catalyzed N-Arylation of Nitroenamines with Diaryliodonium Salts

Klára Aradi, Ádám Mészáros, Balázs L. Tóth, Zoltán Vincze, Z. Novák

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Abstract

A novel synthetic methodology was developed for the N-arylation of nitroenamine derivatives utilizing diaryliodonium triflates and copper(I) chloride as a catalyst. The procedure enables the easy aryl transfer from the hypervalent species under mild catalytic conditions with unusual heteroatom preference and high efficiency.

Original languageEnglish
Pages (from-to)11752-11764
Number of pages13
JournalJournal of Organic Chemistry
Volume82
Issue number22
DOIs
Publication statusPublished - Nov 17 2017

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ASJC Scopus subject areas

  • Organic Chemistry

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