Copolymeric (1R-trans)- N,N′ -1,2-cyclohexylene-bisbenzamide oligodimethylsiloxane chiral stationary phase for gas chromatography

Zoltán Juvancz, Karin E. Markides, Patrik Petersson, Deborah F. Johnson, Jerald S. Bradshaw, Milton L. Lee

Research output: Contribution to journalArticle

8 Citations (Scopus)


A copolymeric stationary phase, consisting of a chiral selective part, i.e. (1R-trans)-N,N′-1,2-cyclohexylenebisbenzamide, and an efficient siloxane oligomeric part, was successfully applied to open tubular column GC analysis. The efficiency and the chiral selectivity of this stationary phase were studied in detail, and high capacity and efficiency at elevated GC temperatures were especially noted. Several drugs and other enantiomeric pairs were separated. The shown examples demonstrate a broad application range for this type of chiral stationary phase in GC analysis.

Original languageEnglish
Pages (from-to)119-126
Number of pages8
JournalJournal of Chromatography A
Issue number1
Publication statusPublished - Dec 20 2002


  • Chiral stationary phases, GC
  • Copolymeric structure
  • Enantiomer separation
  • trans-Cyclohexylenebisbenzamide

ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Organic Chemistry

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