Coordination Complexes of P-Containing Polycyclic Aromatic Hydrocarbons: Optical Properties and Solid-State Supramolecular Assembly

François Riobé, Rózsa Szücs, Christophe Lescop, Régis Réau, László Nyulászi, Pierre Antoine Bouit, Muriel Hissler

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

A series of complexes including σ33-P-modified polycyclic aromatic hydrocarbon (PAH) as a ligand have been prepared showing that the ligand possesses a classical "phosphine-like" reactivity. The use of different metals (Pd(II), Cu(I), Re(I), Au(I)) having different coordination number allows tuning the optical properties of the complexes, which is dominated basically by the electronic transitions of the ligand itself. The study of the solid-state properties by mean of X-ray diffraction also shows that the combination of coordination chemistry and π-stacking interactions between the PAH ligand allows obtaining a great diversity of solid-state structures.

Original languageEnglish
Pages (from-to)2502-2511
Number of pages10
JournalOrganometallics
Volume36
Issue number14
DOIs
Publication statusPublished - Jul 24 2017

    Fingerprint

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this