Controlled Isotope Arrangement in 13C Enriched Carbon Nanotubes

J. Koltai, G. Mezei, V. Zólyomi, J. Kürti, H. Kuzmany, T. Pichler, F. Simon

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

We report the synthesis of a novel isotope engineered 13C-12C heteronuclear nanostructure: single-wall carbon nanotubes made of 13C enriched clusters which are embedded in natural carbon regions. The material is synthesized with a high temperature annealing from 13C enriched benzene and natural C60, which are coencapsulated inside host SWCNTs in an alternating fashion. The Raman 2D line indicates that the 13C isotopes are not distributed uniformly in the inner tubes. A semiempirical method based modeling of the Raman modes under 13C isotope enrichment shows that experimental data is compatible with the presence of 13C rich clusters which are embedded in a natural carbon containing matrix.

Original languageEnglish
Pages (from-to)29520-29524
Number of pages5
JournalJournal of Physical Chemistry C
Volume120
Issue number51
DOIs
Publication statusPublished - Dec 29 2016

Fingerprint

Carbon Nanotubes
Isotopes
Carbon nanotubes
isotopes
carbon nanotubes
Carbon
carbon
Benzene
Nanostructures
benzene
Annealing
tubes
annealing
synthesis
matrices
Temperature

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

Cite this

Koltai, J., Mezei, G., Zólyomi, V., Kürti, J., Kuzmany, H., Pichler, T., & Simon, F. (2016). Controlled Isotope Arrangement in 13C Enriched Carbon Nanotubes. Journal of Physical Chemistry C, 120(51), 29520-29524. https://doi.org/10.1021/acs.jpcc.6b11367

Controlled Isotope Arrangement in 13C Enriched Carbon Nanotubes. / Koltai, J.; Mezei, G.; Zólyomi, V.; Kürti, J.; Kuzmany, H.; Pichler, T.; Simon, F.

In: Journal of Physical Chemistry C, Vol. 120, No. 51, 29.12.2016, p. 29520-29524.

Research output: Contribution to journalArticle

Koltai, J, Mezei, G, Zólyomi, V, Kürti, J, Kuzmany, H, Pichler, T & Simon, F 2016, 'Controlled Isotope Arrangement in 13C Enriched Carbon Nanotubes', Journal of Physical Chemistry C, vol. 120, no. 51, pp. 29520-29524. https://doi.org/10.1021/acs.jpcc.6b11367
Koltai J, Mezei G, Zólyomi V, Kürti J, Kuzmany H, Pichler T et al. Controlled Isotope Arrangement in 13C Enriched Carbon Nanotubes. Journal of Physical Chemistry C. 2016 Dec 29;120(51):29520-29524. https://doi.org/10.1021/acs.jpcc.6b11367
Koltai, J. ; Mezei, G. ; Zólyomi, V. ; Kürti, J. ; Kuzmany, H. ; Pichler, T. ; Simon, F. / Controlled Isotope Arrangement in 13C Enriched Carbon Nanotubes. In: Journal of Physical Chemistry C. 2016 ; Vol. 120, No. 51. pp. 29520-29524.
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