Controlled antioxidative steps of the cell. the concept of chalcogenicity

Béla Fiser, Zoltán Mucsi, Béla Viskolcz, Svend J. Knak Jensen, Imre G. Csizmadia

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The removal of reactive oxygen species by glutathione peroxidase involves reactions where the chalcogens O, S, and Se play a central role. The thermodynamics of the steps in the removal are investigated by electron structure calculations on a series of reactions involving these chalcogens. Analysis of the free energy- and enthalpy changes for the reactions shows a universal linear relationship, called the chalcogenicity, which may be useful in estimating thermodynamic properties in related reactions.

Original languageEnglish
Pages (from-to)83-86
Number of pages4
JournalChemical Physics Letters
Volume590
DOIs
Publication statusPublished - Dec 18 2013

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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