Conformational study of tetramethyl-N,N′-bis-arylcyclodisilazanes by 13C NMR and x-ray diffraction analysis. III. The conformation of tetramethyl-N,N′-bis(O-methoxyphenyl)cyclodisilazane

László Párkányi, László Bihátsi, Pál Hencsei, Áron Szöllösy

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The conformation of tetramethyl-N,N′-bis(o-methoxyphenyl)cyclodisilazane was investigated by 13C NMR in solution and by X-ray diffraction in the solid state. The conformation in solution compares to that of o-methoxyaniline. The phenyl and the cyclodisilazane ring forms a dihedral angle of 7.4° and there is a non-bonded Si ⋯ O distance of 2.73 Å in the crystal. The molecular geometry suggests an analogy to S ⋯ O non-bonded interactions often observed in organosulphur chemistry.

Original languageEnglish
Pages (from-to)7-13
Number of pages7
JournalJournal of Organometallic Chemistry
Volume321
Issue number1
DOIs
Publication statusPublished - Feb 24 1987

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Conformational study of tetramethyl-N,N′-bis-arylcyclodisilazanes by <sup>13</sup>C NMR and x-ray diffraction analysis. III. The conformation of tetramethyl-N,N′-bis(O-methoxyphenyl)cyclodisilazane'. Together they form a unique fingerprint.

  • Cite this