Concerted attack of frustrated Lewis acid-base pairs on olefinic double bonds: A theoretical study

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Abstract

A computational approach reveals cooperative action of the preorganized acidic and basic centers of the frustrated P(t-Bu)3/B(C 6F5)3 Lewis pair on olefinic bonds as the key to the observed regioselective addition reaction.

Original languageEnglish
Pages (from-to)3148-3150
Number of pages3
JournalChemical Communications
Issue number27
DOIs
Publication statusPublished - 2008

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Lewis Acids
Addition reactions
Acids

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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title = "Concerted attack of frustrated Lewis acid-base pairs on olefinic double bonds: A theoretical study",
abstract = "A computational approach reveals cooperative action of the preorganized acidic and basic centers of the frustrated P(t-Bu)3/B(C 6F5)3 Lewis pair on olefinic bonds as the key to the observed regioselective addition reaction.",
author = "A. Stirling and A. Hamza and T. Rokob and I. P{\'a}pai",
year = "2008",
doi = "10.1039/b804662j",
language = "English",
pages = "3148--3150",
journal = "Chemical Communications",
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publisher = "Royal Society of Chemistry",
number = "27",

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