Composition depth profile analysis of electrodeposited alloys and metal multilayers: the reverse approach

Katalin Neuróhr, Attila Csik, Kálmán Vad, András Bartók, György Molnár, László Péter

Research output: Contribution to journalReview article

4 Citations (Scopus)

Abstract

The reverse depth profile analysis is a recently developed method for the study of a deposit composition profile in the near-substrate zone. The sample preparation technique enables one to separate the deposit and a thin cover layer from its substrate, and the initial roughness of the sample is much smaller than in the conventional sputtering direction. This technique is particularly suitable to study the zones being formed in the early phase of the electrodeposition of alloys. It has been demonstrated with the reverse depth profile analysis that in many cases when one component of an alloy is preferentially deposited, an initial zone is formed that is rich in the preferentially deposited component. This phenomenon is demonstrated for Ni-Cd, Ni-Sn, Fe-Co-Ni, Co-Ni, and Co-Ni-Cu alloys. The composition change is confined to the initial 150-nm-thick deposit, and it is the result of the interplay of the deposition preference and the depletion of the electrolyte near the cathode with respect to the ion reduced preferentially. The reverse depth profile analysis made it possible to compare the measured and the calculated composition depth profile of electrodeposited multilayers. It has been shown that the decay in the composition oscillation intensity in Co/Cu multilayers with the increase of the sputtering depth can be derived from the roughness measured as a function of the deposit thickness.

Original languageEnglish
Pages (from-to)2523-2544
Number of pages22
JournalJournal of Solid State Electrochemistry
Volume15
Issue number11-12
DOIs
Publication statusPublished - Dec 1 2011

Keywords

  • Alloy formation
  • Depth profile analysis
  • Electrodeposition
  • Multilayers

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Electrochemistry
  • Electrical and Electronic Engineering

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