Complexation of β-cyclodextrin with a gemini surfactant studied by isothermal titration microcalorimetry and surface tensiometry

Mária Benkö, László A. Király, Sándor Puskás, Zoltán Király

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

We report on the inclusion complex formation of β-cyclodextrin (βCD) with a cocogem surfactant (counterion-coupled gemini surfactant; (bis(4-(2-alkyl)benzenesulfonate)-Jeffamine salt, abbreviated as ABSJ), studied by isothermal titration calorimetry (ITC) and surface tension (SFT) measurements. We measured the critical micelle concentration (cmc) of ABSJ in water by the two experimental techniques in the temperature range 283-343 K, and determined the thermodynamic parameters of the complex formation directly by ITC and indirectly by the SFT. The stoichiometry (N), the binding constant (K), and the enthalpy of complexation were determined, and the Gibbs free energy and the entropy term were calculated from the experimental data. A novel method is presented for the determination of N and K by using surface tensiometry.

Original languageEnglish
Pages (from-to)6756-6762
Number of pages7
JournalLangmuir
Volume30
Issue number23
DOIs
Publication statusPublished - Jun 17 2014

Fingerprint

Cyclodextrins
Calorimetry
Complexation
Titration
Surface-Active Agents
titration
Surface tension
interfacial tension
Surface active agents
heat measurement
surfactants
Critical micelle concentration
Gibbs free energy
Stoichiometry
stoichiometry
Enthalpy
micelles
Entropy
Salts
enthalpy

ASJC Scopus subject areas

  • Electrochemistry
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Materials Science(all)
  • Spectroscopy

Cite this

Complexation of β-cyclodextrin with a gemini surfactant studied by isothermal titration microcalorimetry and surface tensiometry. / Benkö, Mária; Király, László A.; Puskás, Sándor; Király, Zoltán.

In: Langmuir, Vol. 30, No. 23, 17.06.2014, p. 6756-6762.

Research output: Contribution to journalArticle

Benkö, Mária ; Király, László A. ; Puskás, Sándor ; Király, Zoltán. / Complexation of β-cyclodextrin with a gemini surfactant studied by isothermal titration microcalorimetry and surface tensiometry. In: Langmuir. 2014 ; Vol. 30, No. 23. pp. 6756-6762.
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